Ligand labilization gates intramolecular electron transfer in molecular photocatalyst - dataset

The Dataset represents a collection of pump-pulse femtosecond transient absorption spectroscopy data to investigate the effect of temperature and the excess of chloride to the photoinduced reduction of the rhodium center in the supramolecular photocatalytic precursor [(tbbpy)2Ru(tpphz)Rh(Cp*)Cl]Cl(PF6)2 by the change of the corresponding time constant τ3. The Dataset consist of the experimental raw data, Phyton Notebooks which were used to process this data with the help of the Python Package "KiMoPack", as well as excel and origin sheets to analyze the processed data. The valdility of the collected data in regards of the photostability of the sample is supported by the steady-state UV-vis spectra before and after the pump-probe experiments.本数据集收录了一组泵浦脉冲飞秒瞬态吸收光谱（femtosecond transient absorption spectroscopy）数据，用于通过改变对应时间常数τ3，探究温度与过量氯离子对超分子光催化前驱体[(tbbpy)2Ru(tpphz)Rh(Cp*)Cl]Cl(PF6)2中铑中心光诱导还原过程的影响。本数据集包含实验原始数据、借助Python包"KiMoPack"处理该数据的Python代码笔记本，以及用于分析处理后数据的Excel与Origin工作表。泵浦-探测实验前后采集的稳态紫外-可见吸收光谱，可佐证所收集数据在样品光稳定性维度上的有效性。