Research data supporting "Organic Semiconducting Hydrogel with Integrated Microbes and Enzymes for Selective Solar CO2 Conversion"

Each folder in this dataset, named according to the corresponding figure in the manuscript (Figure 1–6 and Figure S1–12), contains an image of the figure (.png) together with the corresponding raw data files (.opju) used to generate the plots. Folders labelled Figure 1–6 contain data associated with the main figures of the manuscript, including the concept and molecular design of an organic semiconducting hydrogel that integrates microbial and enzymatic biocatalysts; synthesis and characterization of the novel polymer CPE-FBI; synthesis and characterization of CPE-FBI hydrogels; photocatalytic H₂ production by CPE-FBI hydrogels; photocatalytic acetate production by microbial biohybrid hydrogels; and photocatalytic formate production by enzyme biohybrid hydrogels. Folders labelled Figure S1–12 contain data for the Supporting Information figures, including the synthetic route to CPE-FBI; ¹H NMR spectra of monomers and polymers; gel permeation chromatography (GPC) analysis of the polymer; cyclic voltammetry characterization; quantitative determination of CPE-FBI covalent crosslinking efficiency; transient absorption spectroscopy of the hydrogels; biocompatibility of the hydrogels with microbes; and the structural and photophysical stability of the microbial biohybrid hydrogels. For detailed descriptions of the experimental procedures, instrumentation, and data collection methods, please refer to the manuscript.

本数据集内的每个文件夹均以稿件中对应图件命名（图1~6及补充图S1~12），文件夹内包含该图的图像文件（.png格式），以及用于生成对应绘图的原始数据文件（.opju格式）。标注为图1~6的文件夹包含与稿件主图相关的数据，涵盖集成微生物与酶促生物催化剂的有机半导体水凝胶的概念与分子设计、新型聚合物CPE-FBI的合成与表征、CPE-FBI水凝胶的合成与表征、CPE-FBI水凝胶的光催化制氢、微生物生物杂化水凝胶的光催化乙酸生成，以及酶促生物杂化水凝胶的光催化甲酸生成。标注为补充图S1~12的文件夹包含支持信息图件对应的数据，涵盖CPE-FBI的合成路线、单体与聚合物的¹H核磁共振（¹H NMR）谱图、聚合物的凝胶渗透色谱（GPC）分析、循环伏安法表征、CPE-FBI共价交联效率的定量测定、水凝胶的瞬态吸收光谱、水凝胶与微生物的生物相容性，以及微生物生物杂化水凝胶的结构与光物理稳定性。如需了解实验流程、仪器设备及数据采集方法的详细说明，请参阅稿件原文。