A New Bimetallic Ferrimagnet ([Mn<sub>2</sub><sup>II</sup>(H<sub>2</sub>O)<sub>2</sub>(CH<sub>3</sub>COO)][Mo<sup>V</sup>(CN)<sub>8</sub>]·2H<sub>2</sub>O)<sub>n</sub> and Its Antiferromagnetic Analogue ([Mn<sub>2</sub><sup>II</sup>(H<sub>2</sub>O)<sub>3</sub>Cl][Mo<sup>V</sup>(CN)<sub>8</sub>]·4H<
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数据链接：
https://figshare.com/articles/dataset/A_New_Bimetallic_Ferrimagnet_Mn_sub_2_sub_sup_II_sup_H_sub_2_sub_O_sub_2_sub_CH_sub_3_sub_COO_Mo_sup_V_sup_CN_sub_8_sub_2H_sub_2_sub_O_sub_n_sub_and_Its_Antiferromagnetic_Analogue_Mn_sub_2_sub_sup_II_sup_H_sub_2_sub_O_sub_3_sub_Cl_Mo_sup_V_sup_CN_sub_8_su/2910901数据链接链接失效反馈
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资源简介：
The reaction between Cs3[Mo(CN)8]·2H2O and MnCl2·4H2O gives two new cyano-bridged bimetallic compounds of ([Mn2II(H2O)2(CH3COO)][MoV(CN)8]·2H2O)n (1) and ([Mn2II(H2O)3Cl][MoV(CN)8]·4H2O)n (2) in different conditions. The magnetic behaviors of these complexes have been investigated, indicating that 1 is a ferrimagnet with an ordering temperature of about 6 K and that for 2 there is antiferromagnetic coupling between the paramagnetic ions in the system.
二水合八氰合钼(V)酸铯（Cs₃[Mo(CN)₈]·2H₂O）与四水合氯化锰(II)（MnCl₂·4H₂O）在不同反应条件下发生反应，可得到两种新型氰基桥联双金属配合物：([Mn₂²⁺(H₂O)₂(CH₃COO)][Moᵛ(CN)₈]·2H₂O)ₙ（编号为1）与([Mn₂²⁺(H₂O)₃Cl][Moᵛ(CN)₈]·4H₂O)ₙ（编号为2）。已对这两种配合物的磁学行为展开研究，结果显示配合物1为亚铁磁体，其磁有序温度约为6 K；配合物2的体系中，顺磁离子之间存在反铁磁耦合作用。
创建时间：
2008-10-01
