ICARUS Chamber Experiment: NCAR_20050211_ETHYL FORMATE_Chlorine radical_No Seed_Cl2 / Ethyl formate photooxidation, 298 K, 50 Torr O2
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https://icarus.ucdavis.edu/experiment/107
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Goals: Determine products of ethyl formate oxidation in the atmosphere. Specifically, investigate atmospheric fate of HC(O)OCH(O.)CH3 radical.Summary: Photolyze Cl2 / ethyl formate / O2 / N2 mixture. Follow loss of ethyl formate and formation of products via FTIROrganization: NCAR Lab Affiliation: NCAR ACOM Boulder CO USA Chamber: NCAR First Floor Stainless SteelExperiment Category: Gas phase chemical reaction Oxidant: Chlorine radical Reactants: ETHYL FORMATE Reaction Type: Photooxidation Temperature: 25 Pressure: 750 Torr
研究目标:明确甲酸乙酯(ethyl formate)在大气中的氧化产物,具体探究HC(O)OCH(O·)CH3自由基在大气中的归趋。实验概要:对氯气/甲酸乙酯/氧气/氮气混合气体进行光解,通过傅里叶变换红外光谱(FTIR)监测甲酸乙酯的消耗与产物生成情况。组织单位:美国国家大气研究中心(NCAR)实验室,附属机构为NCAR ACOM,地处美国科罗拉多州博尔德市。反应腔室:NCAR一楼不锈钢反应腔。实验类别:气相化学反应。氧化剂:氯自由基(Chlorine radical)。反应物:甲酸乙酯(ethyl formate)。反应类型:光氧化反应。实验参数:温度25 ℃,压强750 托(Torr)。
提供机构:
ICARUS Community
创建时间:
2020-12-05



