Ionothermal Synthesis of Homochiral Framework with Acetate-Pillared Cobalt−Camphorate Architecture

A new organically templated homochiral material (EMIm)[Co2(d-cam)2(ac)] (1; d-H2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt−camphorate architecture encapsulating the cationic component of the ionic liquid.

一种新型有机模板同手性材料(EMIm)[Co₂(d-cam)₂(ac)]（编号1；其中d-H₂cam为d-樟脑酸，ac为乙酸根，EMIm为1-乙基-3-甲基咪唑鎓）经离子热法合成，该材料具有独特的乙酸根柱撑钴-樟脑酸盐骨架，可包裹离子液体的阳离子组分。