Phosphorescence decay curves, excitation-emission matrices (EEMs), and input and output parameters of parallel factor analysis for the determination of benzonaphthothiophenes

Excitation-emission matrices (EEMs) for binary mixtures of benzo[b]naptho[1,2-b]thiophene (BbN12T) and benzo[b]naptho[2,1-b]thiophene (BbN21T) and synthetic mixtures of BbN12T and BbN21T with interference were collected at 77K with the aid of a Fluoromax (Horiba Jobin Yvon) using a pulsed lamp, fiber optic probe (FOP), and shpol'skii solvents. These data were subjected to parallel factor analysis (PARAFAC). Phosphorescence decay curves for benzonaphthothiophenes were collected with the aid of a Fluoromax (Horiba Jobin Yvon) using a pulsed lamp, FOP, and shpol'skii solvents. Triplicate spectra of supplemental material at RT, 77K, and 4.2K were also recorded with the aid of a Fluoromax (Horiba Jobin Yvon) using continuous wave lamp, FOP, and shpol'skii solvents. This dataset supports the publication: Al-Tameemi, M., Arif, S., Campiglia, A. D., Wilson, W. B., & Wise, S. A. (2018). Photoluminescence Spectroscopy of Anthrathiophenes and Benzonaphthothiophenes in Shpol’skii Matrixes. Talanta. doi:10.1016/j.talanta.2018.10.044

本数据集包含苯并[b]萘并[1,2-b]噻吩（BbN12T）与苯并[b]萘并[2,1-b]噻吩（BbN21T）的二元混合物，以及BbN12T与BbN21T及干扰物构成的合成混合物的激发发射矩阵（EEMs），所有数据于77K条件下采集，采集过程中使用Horiba Jobin Yvon公司的Fluoromax光谱仪，搭配脉冲灯、光纤探头（FOP）及Shpol’skii溶剂。上述数据已通过平行因子分析（PARAFAC）进行处理。苯并萘并噻吩类化合物的磷光衰减曲线同样采用Horiba Jobin Yvon公司的Fluoromax光谱仪，搭配脉冲灯、光纤探头（FOP）及Shpol’skii溶剂完成采集。补充材料的三次重复光谱分别在室温（RT）、77K及4.2K下记录，采集设备同样为Horiba Jobin Yvon公司的Fluoromax光谱仪，搭配连续波灯、光纤探头（FOP）及Shpol’skii溶剂。本数据集支撑以下已发表研究成果：Al-Tameemi, M., Arif, S., Campiglia, A. D., Wilson, W. B., & Wise, S. A. (2018). 《Shpol’skii基质中蒽并噻吩与苯并萘并噻吩类化合物的光致发光光谱》. Talanta. 数字对象标识符（DOI）：10.1016/j.talanta.2018.10.044