Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation
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https://figshare.com/articles/dataset/Oxidative_1_2-Difunctionalization_of_Ethylene_via_Gold-Catalyzed_Oxyarylation/5375113
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Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.
在氧化金催化(oxidative gold catalysis)反应条件下,使乙烯与芳基硅烷和醇类发生反应,可生成1,2-氧芳基化(1,2-oxyarylation)产物。该过程为实现这类基础化工原料的催化差异化1,2-双官能化提供了罕见的实例。
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2017-11-10



