Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.在氧化金催化（oxidative gold catalysis）反应条件下，使乙烯与芳基硅烷和醇类发生反应，可生成1,2-氧芳基化（1,2-oxyarylation）产物。该过程为实现这类基础化工原料的催化差异化1,2-双官能化提供了罕见的实例。