Asymmetric Construction of Functionalized Bicyclic Imides via [3 + 2] Annulation of MBH Carbonates Catalyzed by Dipeptide-Based Phosphines
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https://figshare.com/articles/dataset/Asymmetric_Construction_of_Functionalized_Bicyclic_Imides_via_3_2_Annulation_of_MBH_Carbonates_Catalyzed_by_Dipeptide_Based_Phosphines/2503726
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A highly enantioselective [3 + 2] annulation of MBH carbonates and maleimides catalyzed by chiral phosphines has been developed. In the presence of 5 mol % of l-Thr-l-Val-derived phosphine 6, functionalized bicyclic imides were prepared in excellent yields, and with high diastereoselectivities and nearly perfect enantioselectivities.
创建时间：
2016-02-20
