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Synthesis and Structures of Platinum(0) Alkyne Complexes with Extended π-Conjugated Systems

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https://figshare.com/articles/dataset/Synthesis_and_Structures_of_Platinum_0_Alkyne_Complexes_with_Extended_Conjugated_Systems/2939944
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资源简介:
1,2-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobuta[l]phenanthrene (DPCB-phen) as a low-coordinated phosphorus ligand forms the platinum(0) alkyne complexes [Pt(alkyne)(DPCB-phen)] with extended π-conjugated systems. The colors of the complexes are highly dependent on alkyne ligands, showing a marked variation from reddish orange to teal.
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2008-05-12
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