Synthetic Entry into 1‑Phosphono-3-azabicyclo[3.1.0]hexanes
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https://figshare.com/articles/dataset/Synthetic_Entry_into_1_Phosphono_3_azabicyclo_3_1_0_hexanes/2379619
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资源简介：
3-Azabicyclo[3.1.0]hex-2-en-1-yl
phosphonates were prepared in
a five-step reaction route from β-ketophosphonates. The key
steps in this sequence are an atom-transfer radical cyclization and
an unforeseen lithium–halogen exchange with n-BuLi. The cyclization reaction proceeds with excellent diastereoselectivity.
The resulting cyclic imines were reduced, and 3-azabicyclo[3.1.0]hexan-1-yl
phosphonates were obtained.
创建时间：
2013-09-06
