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A Novel Family of Phosphole-Thiophene Oligomers for Optoelectronic Applications

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/A_Novel_Family_of_Phosphole_Thiophene_Oligomers_for_Optoelectronic_Applications/2901436
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A 2-terthienylphospholide can be prepared from a 1-terthienylphosphole by reaction with tBuOK in diglyme at 150 °C. This phospholide is then transformed into the corresponding 1-methyl-2-terthienylphosphole-borane. This borane complex fluoresces at 510 nm in CH2Cl2 with a quantum yield of 0.17. The excited-state displays a significant charge transfer between the terthienyl substituent and the phosphole ring as shown by the shift of the emission to lower energies upon increasing the polarity of the solvent.
创建时间:
2016-02-27
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