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Gold-Catalyzed Stereocontrolled Oxacyclization/[4+2]-Cycloaddition Cascade of Ketone-Allene Substrates

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https://figshare.com/articles/dataset/Gold_Catalyzed_Stereocontrolled_Oxacyclization_4_2_Cycloaddition_Cascade_of_Ketone_Allene_Substrates/2753077
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资源简介:
We report the first success on the Au-catalyzed tandem oxacyclization/[4+2]-cycloaddition cascade using ketone-allene substrates to give highly substituted oxacyclics with excellent stereocontrol. In contrast to oxo-alkyne substrates, the resulting cycloadducts are isolable and efficiently produced from a reasonable scope of enol ethers.
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2010-07-14
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