Stereocontrolled and Adaptable Synthesis of (–)-Aspergilone A via the Key Intermediate (+)-Phenol A

This dataset contains the analytical data for (-)-aspergilone A, the enantiomer of the naturally occurring (+)-aspergilone A, its synthetic intermediates and in house synthesized reagents. The analytical data includes NMR raw data, IR spectra and chiral SFC PDA traces as csv files as well as chiral HPLC PDA traces and HRMS spectra as PDF files. The structure of all compounds can be found in the data files. Synthetic procedures as available through the Supporting Information of the associated publication.

本数据集包含(-)-曲霉酮A[(-)-aspergilone A]的分析数据，该化合物为天然存在的(+)-曲霉酮A[(+)-aspergilone A]的对映异构体，同时涵盖其合成中间体与内部合成试剂的相关分析数据。
分析数据包含以CSV格式存储的核磁共振（Nuclear Magnetic Resonance, NMR）原始数据、红外（Infrared, IR）光谱、手性超临界流体色谱-光电二极管阵列检测（Supercritical Fluid Chromatography-PDA, SFC-PDA）图谱；以及以PDF格式存储的手性高效液相色谱-光电二极管阵列检测（High Performance Liquid Chromatography-PDA, HPLC-PDA）图谱与高分辨质谱（High Resolution Mass Spectrometry, HRMS）光谱。
所有化合物的结构均可在数据文件中查阅，合成步骤可通过相关出版物的补充材料获取。