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Disassembly and Reassembly of Polyoxometalates: The Formation of Chains from an Adaptable Precursor

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Disassembly_and_Reassembly_of_Polyoxometalates_The_Formation_of_Chains_from_an_Adaptable_Precursor/2795305
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Two one-dimensional chain complexes with building blocks comprised of polyoxotungstate-ligated lanthanoid centers have been synthesized from the adaptable precursor [As2W19O67(H2O)]14− through combined disassembly and reassembly processes. Careful control of the reaction and crystallization conditions affords compounds formulated as H3K7Na6[Nd3As4W41O141OH(H2O)10]·60H2O (1) and KNa[Dy4As2W22O76(H2O)19(C2H5NO2)2]·20.5H2O (2).
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2016-02-25
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