The tert-Butyl Side Chain: A Powerful Means to Lock Peptoid Amide Bonds in the Cis Conformation
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/The_i_tert_i_Butyl_Side_Chain_A_Powerful_Means_to_Lock_Peptoid_Amide_Bonds_in_the_Cis_Conformation/2419006
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The very simple sterically hindered tert-butyl side chain exerts complete control over the peptoid amide geometry which only exists in the cis conformation. It is exemplified in NtBu glycine homo-oligomers and in linear oligopeptoids designed with an alternating cis–trans backbone amide pattern.
创建时间:
2016-02-19



