Star-Shaped Pyrrole-Fused Tetrathiafulvalene Oligomers: Synthesis and Redox, Self-Assembling, and Conductive Properties
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Star_Shaped_Pyrrole_Fused_Tetrathiafulvalene_Oligomers_Synthesis_and_Redox_Self_Assembling_and_Conductive_Properties/2625886
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A series of star-shaped pyrrole-fused tetrathiafulvalene (TTF) oligomers 1–3 was synthesized via an SNAr reaction of fluorinated benzenes with the pyrrolyl sodium salts. Electrochemical and chemical oxidations of 1–3 revealed that a radical cation moiety on each TTF unit was successfully accumulated in all oligomers. Self-assembled structures of neutral and oxidized species were characterized by SEM and XRD, and their conductive properties of the iodine-doped 1–3 as well as an intermolecular mixed-valence ion radical salt were investigated.
创建时间：
2016-02-23
