Conformationally Distorted π‑Conjugation for Reaction-Based Detection of Nickel: Fluorescence Turn-on by Twist-and-Fragment
收藏Figshare2016-09-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Conformationally_Distorted_Conjugation_for_Reaction-Based_Detection_of_Nickel_Fluorescence_Turn-on_by_Twist-and-Fragment/3756864
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A conformationally twisted N-arylbenzotriazole was designed as a fluorescence turn-on molecular probe. Under ambient conditions, metal-catalyzed deallylation reactions restore an intense blue emission. This reaction scheme is applicable exclusively to Group 10 transition metal ions and optimized, in particular, for nickel to allow sub-micromolar detection with no competition from other first-row transition-metal ions.
创建时间：
2016-09-12
