Stereospecific Alkene Aziridination Using a Bifunctional Amino-Reagent: An Aza-Prilezhaev Reaction
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https://figshare.com/articles/dataset/Stereospecific_Alkene_Aziridination_Using_a_Bifunctional_Amino-Reagent_An_Aza-Prilezhaev_Reaction/7462046
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资源简介：
In
situ deprotection (TFA) of O-Ts activated N-Boc hydroxylamines
triggers intramolecular aziridination of N-tethered alkenes to provide
complex N-heterocyclic ring systems. Synthetic and computational studies
corroborate a diastereospecific aza-Prilezhaev-type mechanism. The
feasibility of related intermolecular alkene aziridinations is also
demonstrated.
创建时间：
2018-12-13
