Large Mid-IR Second-Order Nonlinear-Optical Effects Designed by the Supramolecular Assembly of Different Bond Types without IR Absorption
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https://figshare.com/articles/dataset/Large_Mid_IR_Second_Order_Nonlinear_Optical_Effects_Designed_by_the_Supramolecular_Assembly_of_Different_Bond_Types_without_IR_Absorption/2390839
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资源简介：
Two
new different-bond-type hybrid compounds, (Hg6P4Cl3)(PbCl3) (1) and (Hg23P12)(ZnCl4)6 (2), with
supramolecular interactions between host and guest moieties, which
based on metal–pnicogen, pnicogen–pnicogen, and metal–halogen
bonds were obtained by solid-state reactions. Compounds 1 and 2 show large second-harmonic-generation (SHG) activity
and are transparent in the wide mid-IR region, providing an effective
route for searching new IR nonlinear-optical material systems by combining
two or more different bond types with no IR absorption within a single
compound through supramolecular assembly. Theory predications based
on first-principles calculations are also performed on the SHG properties
of 1 and 2.
创建时间：
2013-08-05
