1,2-Diphosphonium Dication: A Strong P‑Based Lewis Acid in Frustrated Lewis Pair (FLP)-Activations of B–H, Si–H, C–H, and H–H Bonds
收藏Figshare2016-02-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/1_2_Diphosphonium_Dication_A_Strong_P_Based_Lewis_Acid_in_Frustrated_Lewis_Pair_FLP_Activations_of_B_H_Si_H_C_H_and_H_H_Bonds/2157775
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A highly Lewis acidic diphosphonium dication [(C10H6)(Ph2P)2]2+ (1), in combination with a Lewis basic phosphine, acts as a purely phosphorus-based frustrated Lewis pair (FLP) and abstracts hydride from [HB(C6F5)3]− and Et3SiH demonstrating the remarkable hydridophilicity of 1. The P-based FLP is also shown to activate H2 and C–H bonds.
创建时间：
2016-02-13
