Switching from Bonding to Nonbonding: Temperature-Dependent Metal Coordination in a Zinc(II) Sulfadiazine Complex
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https://figshare.com/articles/dataset/Switching_from_Bonding_to_Nonbonding_Temperature_Dependent_Metal_Coordination_in_a_Zinc_II_Sulfadiazine_Complex/2560603
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资源简介:
The metal coordination in the mononuclear complex diamminebis(sulfadiazine)zinc
shows a unique temperature dependence: High-resolution diffraction
data prove that the coordination is almost tetrahedral at 100 K, whereas
a fifth longer interaction becomes relevant at 200 K. The change in
the geometry is fully reversible and is also reflected in the charge
density of the compound.
创建时间:
2016-02-22



