A General Method for the Catalytic Nazarov Cyclization of Heteroaromatic Compounds
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https://figshare.com/articles/dataset/A_General_Method_for_the_Catalytic_Nazarov_Cyclization_of_Heteroaromatic_Compounds/3046522
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资源简介：
A general, catalytic method for efficient Nazarov cyclization of systems containing heteroaromatic components has been developed. Scandium
triflate was identified as the most reactive promoter, and it was found that addition of lithium perchlorate was necessary for synthetically
useful catalytic cyclizations. The method was used to synthesize a range of cyclopentanone-fused heteroaromatic systems in 36−97% yield,
and the reactivity trends observed demonstrate the impact of polarization on cyclization efficiency.
创建时间：
2016-02-29
