A Series of Coordination Polymers Constructed from a Multidentate N‑Donor Ligand and Varied Carboxylate Anions: Syntheses, Structures, and Luminescent Properties
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https://figshare.com/articles/dataset/A_Series_of_Coordination_Polymers_Constructed_from_a_Multidentate_N_Donor_Ligand_and_Varied_Carboxylate_Anions_Syntheses_Structures_and_Luminescent_Properties/2371282
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资源简介：
Ten
new coordination polymers, [Zn2(Htrb)(L1)2]·8H2O (1), [Zn2(Htrb)(HL2)2(H2O)2]·4H2O (2), [Co2(Htrb)(HL2)2(H2O)2]·4H2O (3), [Cd2(Htrb)(HL2)2(H2O)2]·4H2O (4), [Cu3(Htrb)(L2)2(H2O)2]·8H2O (5), [Ag5(Htrb)(HL2)(L2)(H2O)2]·2H2O (6), [Ag6(Htrb)2(HL3)2(L4)]·2H3L3·6H2O (7), [Ag4(Htrb)2(H2L5)2] (8), [Ag6(Htrb)2(HL6)2(H2O)3]·2H2O (9), and
[Ag2(Htrb)]·2NO3 (10), based on a hexadentate N-donor ligand hexakis(1,2,4-triazol-ylmethy1)benzene
(Htrb) and different carboxylates, have been synthesized (H2L1 = 5-OH-1,3-benzenedicarboxylic acid, H3L2 = 1,3,5-benzenetricarboxylic
acid, H3L3 = 1,2,4-benzenetricarboxylic acid, H2L4 = 2-CH2OH-1,4-benzenedicarboxylic acid, H4L5 = 3,3′,4,4′-benzophenone tetracarboxylate acid,
and H4L6 = 4,4′-oxidiphthalic acid). Compounds 1–4 feature typical 2D binodal 4-connected
networks with a (4·64·8)2(42·64) topology. Compound 5 exhibits
a 3D (4,6)-connected (44·62)(44·610·8) framework. Compound 6 shows a 3D trinodal (6,8)-connected framework with a (34·44·52·65)2(34·412·54·68) topology. Compound 7 features an unusual 3D
trinodal (4,6)-connected net with a (32·62·72)(3·4·5·62·8)2(32·42·52·64·72·83) topology.
Compound 8 displays a 2D layer with a (3,4)-connected
(4·62)2(42·62·82) topology. Compound 9 shows
a uninodal 2D 4-connected network with a (44)(62) topology. Compound 10 reveals a 3D (4,8)-connected
(46)2(412·612·84) net. The ligand effects on the complex structures
were studied. Moreover, their luminescent emissions were studied at
room temperature.
创建时间：
2013-10-02
