Hydroxyl-Directed Stereoselective Diboration of Alkenes
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https://figshare.com/articles/dataset/Hydroxyl_Directed_Stereoselective_Diboration_of_Alkenes/2035587
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An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that the process represents a method for the stereoselective directed dihydroxylation of alkenes.
创建时间：
2015-12-17
