Synthesis of Highly Cis, Syndiotactic Polymers via Ring-Opening Metathesis Polymerization Using Ruthenium Metathesis Catalysts
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Highly_Cis_Syndiotactic_Polymers_via_Ring_Opening_Metathesis_Polymerization_Using_Ruthenium_Metathesis_Catalysts/2397274
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The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.
创建时间：
2016-02-19
