Enantioselective, Catalytic Trichloromethylation through Visible-Light-Activated Photoredox Catalysis with a Chiral Iridium Complex
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下载链接：
https://figshare.com/articles/dataset/Enantioselective_Catalytic_Trichloromethylation_through_Visible_Light_Activated_Photoredox_Catalysis_with_a_Chiral_Iridium_Complex/2202688
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资源简介：
An
enantioselective, catalytic trichloromethylation of 2-acyl imidazoles
and 2-acylpyridines is reported. Several products are formed with
enantiomeric excess of ≥99%. In this system, a chiral iridium
complex serves a dual function, as a catalytically active chiral Lewis
acid and simultaneously as a precursor for an in situ assembled visible-light-triggered photoredox catalyst.
创建时间：
2016-02-15
