Ruthenium–Cobalt Bimetallic Supramolecular Cages via a Less Symmetric Tetrapyridyl Metalloligand and the Effect of Spacer Units
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https://figshare.com/articles/dataset/Ruthenium_Cobalt_Bimetallic_Supramolecular_Cages_via_a_Less_Symmetric_Tetrapyridyl_Metalloligand_and_the_Effect_of_Spacer_Units/2121961
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资源简介：
The
self-assembly of Cs-symmetric
tetrapyridyl cobalt–metalloligand 2 with three half-sandwich diruthenium acceptors, 3–5, led to the formation of A4D2 (A = acceptor, D = donor) metallacages 6–8, as shown by ESI mass spectrometry, NMR spectroscopy,
and X-ray crystallography. The solid-state structures of 6–8 revealed that the length of the acceptor unit
greatly influences the molecular packing of these metallacages.
Hence, in the solid state, 6–8 can
be considered to have waterwheel-shaped, tweezer-shaped, and
butterfly-like architectures, respectively.
创建时间：
2016-02-12
