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Hydrogen-Bonded Assembly of Water and Chloride in a 3D Supramolecular Host

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Hydrogen_Bonded_Assembly_of_Water_and_Chloride_in_a_3D_Supramolecular_Host/3245911
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The hydrogen-bonded water-chloride assembly {[(H2O)14Cl2]2-}n, which is stabilized in a template of metal organic supramolecular host (MOSH) {[Cu4(phen)4(adi)(OH)2Cl2]2+}n(adi = adipate dianion; phen = 1,10-phenanthroline), was isolated. DFT calculations corroborate the X-ray crystal structure of the hydrogen-bonded water-chloride assembly. The variable temperature magnetic study also corroborates the single-crystal structure.
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2016-05-05
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