Catalytic Conversion of Alcohols to Carboxylic Acid Salts and Hydrogen with Alkaline Water
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https://figshare.com/articles/dataset/Catalytic_Conversion_of_Alcohols_to_Carboxylic_Acid_Salts_and_Hydrogen_with_Alkaline_Water/4776451
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资源简介：
A [RuH(CO)(py-NP)(PPh3)2]Cl (1) catalyst is found to be
effective for catalytic transformation of primary alcohols, including
amino alcohols, to the corresponding carboxylic acid salts and two
molecules of hydrogen with alkaline water. The reaction proceeds via
acceptorless dehydrogenation of alcohol, followed by a fast hydroxide/water
attack to the metal-bound aldehyde. A pyridyl-type nitrogen in the
ligand architecture seems to accelerate the reaction.
创建时间：
2017-03-22
