Chiral Hydride and Dihydrogen Pincer-Type Complexes of Osmium
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https://figshare.com/articles/dataset/Chiral_Hydride_and_Dihydrogen_Pincer-Type_Complexes_of_Osmium/12074799
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资源简介：
Reaction of [OsCl6]2- with a pincer-type ligand, (S)-But2PCH2CH(NMe2)C3H6PBut2, afforded a chiral
square-pyramidal 16-electron carbene complex, OsCl(PGP) (1), PGP = [κ4-But2PCH2CH(N(Me)CH)CHC2H4PBut2], in excellent yield. Reactions of 1 with hydrogen under different conditions resulted in
the hydride and dihydrogen species OsH2Cl(PGP), [Os(H2)2(PGP)]+, and OsH3(PGP), which have been
characterized by a combination of spectroscopic and DFT computational techniques.
创建时间：
2007-11-05
