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Polymorphism-Dependent Spin-Crossover: Hysteretic Two-Step Spin Transition with an Ordered [HS–HS–LS] Intermediate Phase

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https://figshare.com/articles/dataset/Polymorphism_Dependent_Spin_Crossover_Hysteretic_Two_Step_Spin_Transition_with_an_Ordered_HS_HS_LS_Intermediate_Phase/2163076
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资源简介:
A mononuclear iron­(II) complex has been isolated in two polymorphs. Polymorph 1b remains high-spin over all temperatures, whereas polymorph 1a undergoes a cooperative two-step spin crossover accompanied by symmetry breaking, showing an ordered 2:1 high-spin–low-spin intermediate phase.
创建时间:
2016-02-13
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