遇见数据集

Polymorphism-Dependent Spin-Crossover: Hysteretic Two-Step Spin Transition with an Ordered [HS–HS–LS] Intermediate Phase

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A mononuclear iron­(II) complex has been isolated in two polymorphs. Polymorph 1b remains high-spin over all temperatures, whereas polymorph 1a undergoes a cooperative two-step spin crossover accompanied by symmetry breaking, showing an ordered 2:1 high-spin–low-spin intermediate phase.

创建时间:
2016-02-13
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