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A New Ruthenium Complex with an Electron-Donating Aminoindenyl Ligand for Fast Metal-Mediated Living Radical Polymerizations

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NIAID Data Ecosystem2026-03-06 收录
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A new ruthenium complex with an electron-donating aminoindenyl ligand induces a fast living radical polymerization of methyl methacrylate (MMA) in the presence of a chloride initiator to give polymers with controlled and variable molecular weights (Mn = 103−105) and very narrow molecular weight distributions (Mw/Mn < 1.1). The structure and high activity of the catalyst were analyzed by X-ray crystallography and cyclic voltammetry in comparison to those of a similar complex with an indenyl ligand.

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2016-08-18
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