Pyrrospirones K-Q, Decahydrofluorene-class Alkaloids from the Marine-Derived Fungus Penicillium sp. SCSIO 41512
收藏南海海洋数据中心2024-03-01 收录
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https://data.scsio.ac.cn/metaData-detail/1564516431053611008
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从海洋真菌青霉菌中分离到7种新的十氢氟类生物碱吡咯螺旋酮K-Q(1-7)和6种已知的类似物(8-13)。通过大量的光谱分析确定了它们的结构,并通过单晶x射线衍射分析和圆二色光谱(ECD)的量子化学计算确定了它们的绝对构型。
Seven new decahydrofluorene-type pyrrolo-spiroketone alkaloids designated K–Q (1–7) and six known analogs (8–13) were isolated from a marine fungus of the genus Penicillium. Their structures were elucidated through extensive spectroscopic analyses, and their absolute configurations were unambiguously determined by single-crystal X-ray diffraction analysis and quantum chemical calculations of their electronic circular dichroism (ECD) spectra.
提供机构:
中国科学院南海海洋研究所



