Self-Assembly of Tripyrazolate-Linked Macrotricyclic M12L4 Cages with Dimetallic Clips
收藏acs.figshare.com2023-05-30 更新2025-03-26 收录
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https://acs.figshare.com/articles/dataset/Self_Assembly_of_Tripyrazolate_Linked_Macrotricyclic_M_sub_12_sub_L_sub_4_sub_Cages_with_Dimetallic_Clips/3016525/1
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The self-assembly in aqueous solution of tripyrazolate trianion linkers (H3L = 1 and 2) with coordinated dimetallic clips leads to the formation
of Pd12L4 cages with interior cavities of 1800 Å3 and 1500 Å3, respectively, confirmed by 1H NMR, 13C NMR, cold spray ionization mass
spectrometry (CSI-MS), and single-crystal X-ray analysis.
在水溶液中,三吡唑基三阴离子连接体(H3L = 1 和 2)与配位双金属夹具的自组装过程,产生了具有1800 ų和1500 ų内腔的Pd12L4笼状结构,此结构通过1H NMR、13C NMR、冷喷雾电离质谱法(CSI-MS)以及单晶X射线分析得到证实。
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