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Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand

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Figshare2016-02-13 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Low_Coordinate_Cobalt_I_Complexes_Stabilized_by_an_Extremely_Bulky_Amide_Ligand/2160607
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A series of low-coordinate, high-spin, mono- and dinuclear cobalt­(I) complexes bearing an extremely bulky amide (L″ = N­(Ar*)­(SiPh3); Ar* = C6H2{C­(H)­Ph2}2Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt­(I) complex, [L″Co­(IPriMe)] (IPriMe = :C­{N­(Pri)­C­(Me)}2), which has a near-linear cobalt coordination geometry.
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2016-02-13
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