Relay Rh(II)/Pd(0) Dual Catalysis: Selective Construction of Cyclic All-Quaternary Carbon Centers
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下载链接：
https://figshare.com/articles/dataset/Relay_Rh_II_Pd_0_Dual_Catalysis_Selective_Construction_of_Cyclic_All-Quaternary_Carbon_Centers/4126704
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资源简介：
A novel
relay Rh(II)/Pd(0) dual catalysis strategy that promotes the divergent
reaction of α-diazo-carbonyl compounds with allylic carboxylates
for the selective construction of cyclic all-quaternary carbon centers
has been developed. This binary catalyst system rendered domino C–H
insertion/allylic alkylation process under mild conditions. Remarkably,
the domino catalytic reaction shows good selectivity and excellent
tolerance to various functionalities and is operationally simple.
创建时间：
2016-11-14
