Guest Molecule Release Triggers Changes in the Catalytic and Magnetic Properties of a FeII-Based 3D Metal–Organic Framework
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A FeII-based metal–organic framework (MOF), {[Fe2(pbt)2(H2O)2]·2H2O}n, undergoes an irreversible dehydration, which triggers changes in the catalytic and magnetic properties of the MOF. These property changes are attributed to the high-spin to low-spin transition of 7.1% center FeII, which is demonstrated by 57Fe Mössbauer, X-ray photoelectron spectroscopy, and UV/vis absorption spectra.
创建时间：
2016-02-17
