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Combining Cyanometalates and Coordination Clusters: An Alternative Synthetic Route toward Original Molecular Materials

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Combining_Cyanometalates_and_Coordination_Clusters_An_Alternative_Synthetic_Route_toward_Original_Molecular_Materials/2371519
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As an original synthetic route to molecular magnetic materials, we have reacted partially-blocked cyanometalates with preformed coordination cluster. The association of the fac-[Fe­(Tp)­(CN)3]− assembling metalloligand with the [Cu3(OH)­(pz)3]2+ trigonal cluster has afforded a novel coordination network where the trimetallic copper­(II) nodes are linked by the iron­(III) complexes into chains and by coordinating acetate into a two-dimensional framework.
创建时间:
2016-02-18
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