Synthesis and Structure of Cationic Phosphine Gold(I) Enol Ether Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Cationic_Phosphine_Gold_I_Enol_Ether_Complexes/2470468
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Cationic {[(t-Bu)2(o-biphenyl)P]Au(enol ether)}+SbF6– and {[(t-Bu)3P]Au(enol ether)}+SbF6– complexes were isolated and characterized by NMR spectroscopy and X-ray crystallography. For three of the four complexes characterized in the solid state, gold coordinates to the electron-rich bond in a η1 fashion, while a 2,3-dihydrofuran complex displays η2 coordination.
创建时间：
2016-02-20
