Heteronuclear RuIIAgI Complexes Having a Pyrroloquinolinequinone Derivative as a Bridging Ligand
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Heteronuclear_Ru_sup_II_sup_Ag_sup_I_sup_Complexes_Having_a_Pyrroloquinolinequinone_Derivative_as_a_Bridging_Ligand/2437954
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资源简介：
Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAgI units were linked by two [AgI(OTf)2]− units (OTf = CF3SO3–). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.
创建时间：
2016-02-19
