Catalytic Asymmetric Ring Openings of Meso and Terminal Aziridines with Halides Mediated by Chiral 1,2,3-Triazolium Silicates
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https://figshare.com/articles/dataset/Catalytic_Asymmetric_Ring_Openings_of_Meso_and_Terminal_Aziridines_with_Halides_Mediated_by_Chiral_1_2_3_Triazolium_Silicates/2518861
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资源简介：
Catalytic asymmetric chloride and bromide ring openings
of meso
aziridines with trimethylsilyl halides have been developed using modular
chiral 1,2,3-triazolium chlorides as catalysts. Control experiments
suggest the reaction pathway involving hypervalent silicate ions as
reactive intermediates. The application of this system to the efficient
kinetic resolution of terminal aziridines is also reported.
创建时间：
2016-02-20
