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Borinic Acid Catalyzed, Regioselective Chloroacylations and Chlorosulfonylations of 2,3-Epoxy Alcohols

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https://figshare.com/articles/dataset/Borinic_Acid_Catalyzed_Regioselective_Chloroacylations_and_Chlorosulfonylations_of_2_3_Epoxy_Alcohols/2148982
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In the presence of a borinic acid derived catalyst, 2,3-epoxy alcohols undergo couplings with acyl and sulfonyl chlorides. This transformation directly generates O-acylated or O-sulfonylated chlorohydrin diols, with significant levels of regioselectivity for both the ring-opening and O-functionalization steps.
创建时间:
2016-02-13
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