Insertion of a N-Heterocyclic Carbene (NHC) into a Platinum−Olefin Bond
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https://figshare.com/articles/dataset/Insertion_of_a_N-Heterocyclic_Carbene_NHC_into_a_Platinum_Olefin_Bond/12077976
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资源简介:
The insertion of a N-heterocyclic carbene (NHC) into
a coordinated olefin moiety is observed for a Pt-based system.
Important intermediates along the reaction pathway have been
isolated and fully characterized. Computational work supports
a proposed mechanistic pathway involving external attack at
the olefin by a NHC ligand rather than an intramolecular
migratory insertion route.
创建时间:
2007-07-02



