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Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Isolation_of_the_Large_Actinide_sub_38_sub_Poly_oxo_Cluster_with_Uranium/2363488
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By controlling the water content, a new poly-oxo-metalate species containing 38 uranium centers has been solvothermally synthesized in the presence of benzoic acid in tetrahydrofuran (THF). The {U38} motif contains a distorted UO2 core of fluorite type, stabilized by benzoate and THF molecules. This compound is analogous to the {Pu38} motif and was characterized by X-ray photoelectron spectroscopy and magnetic analyses.
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2016-02-18
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