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Fluorine-Induced Chiral Coordination Arrays Containing Helical Hydrogen-Bonding Chains of Water or Fluorinated Ligand

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Fluorine_Induced_Chiral_Coordination_Arrays_Containing_Helical_Hydrogen_Bonding_Chains_of_Water_or_Fluorinated_Ligand/2574079
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资源简介:
Two chiral d10 metallosupramolecular systems based on an achiral fluorinated Schiff-base ligand have been prepared and characterized. The ZnII complex 1 reveals 21 helical coordination chains with the inclusion of rare water chains of opposite helix in the perpendicular channels, whereas the CdII complex 2 displays the homochiral 1D coordination motifs with 31 symmetry and a 3D supramolecular architecture built by C–H···F interactions.
创建时间:
2011-12-07
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