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Dimeric Rh Complexes Supported by a Bridging Phosphido/Bis(Phosphine) PPP Ligand

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Figshare2024-04-22 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Dimeric_Rh_Complexes_Supported_by_a_Bridging_Phosphido_Bis_Phosphine_PPP_Ligand/25665558
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Rh complexes of a tridentate PPP ligand bearing 1,2-pyrrolediyl linkers have been prepared, including examples with the central P donor being either a phosphine or a phosphide. Three bimetallic Rh complexes containing the diamandoid Rh2P2 core (P = phosphido) have been structurally and spectroscopically characterized. The Rh–Rh interaction in these three dimers was examined by way of structural comparisons and DFT investigations.
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2024-04-22
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