Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation
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https://figshare.com/articles/dataset/Enantioselective_Desymmetrization_of_Cyclopropenes_by_Hydroacylation/2710330
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We report an enantioselective desymmetrization of cyclopropenes by intermolecular Rh-catalyzed hydroacylation. Cyclopropylketones, bearing quaternary stereocenters, are produced with diastereocontrol (up to >20:1) and excellent enantiomeric excess (up to >99 ee).
创建时间:
2010-11-24



