2‑Hydro-2-aminophosphasilene with N–Si–P π Conjugation
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/2_Hydro_2_aminophosphasilene_with_N_Si_P_Conjugation/2452735
下载链接
链接失效反馈官方服务：
资源简介：
The first 2-aminophosphasilene, [Ar(Me3Si)N]HSiPAr′
(4, Ar = 2,6-iPr2C6H3, Ar′ = 2,6-Mes2C6H3), bearing a hydride ligand on the three-coordinate silicon
atom has been synthesized and structurally characterized. Both X-ray
data of 4 and DFT calculations on the model compound
(H2N)HSiPH (4′) disclosed that
the amino group on the silicon atom results in significant N–Si–P
π conjugation.
创建时间：
2016-02-20
